Topological Sorting is an ordering of nodes in a directed acyclic graph (DAG) where each node appears before all the nodes it points to. It is like creating a list of tasks, ensuring that each task comes after any tasks it depends on. The sorting can be achieved using Kahn's algorithm or DFS with a stack. Kahn's algorithm works by repeatedly removing nodes with no incoming edges (zero in-degree) and adding them to the order.